Synthesis of dihydrodehydrodiconiferyl alcohol: the revised structure of lawsonicin.
نویسندگان
چکیده
Structural revision of lawsonicin, a natural product of Lawsonia alba, is reported based upon comparison of its spectral data with that of the naturally occurring dihydrobenzo[b]furan neolignan (rac)-trans-dihydrodehydrodiconiferyl alcohol, which is found to be identical. A concise synthesis of dihydrodehydrodiconiferyl alcohol, via Rh(2)[S-DOSP](4)-catalysed intramolecular C-H insertion, is described.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 8 1 شماره
صفحات -
تاریخ انتشار 2010